Sulfide stress cracking nace mr01752002, mr0175iso. Stress corrosion cracking scc results from the combined action of three factors. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. The effects of sulfide stress cracking on the mechanical properties and intergranular cracking of p110 casing steel in sour environments article in petroleum science 103. Lonestar technical services llc one stop solution for. The effects of sulfide stress cracking on the mechanical properties and intergranular cracking of p110 casing steel in sour environments springerlink. Various techniques are utilized to grade the steel types considering their resistance to scc and the. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Testing laboratory testing can be carried out according to nace tm0177 5% nacl and 0. An intergranular attack iga problem in a type 304l stainlessclad compound plate kraft digester was investigated using both insitu corrosion probes and laboratory autoclaves filled with. A wide variety of routine tests are conducted at lonestar to determine intergranular corrosion attack, weight loss corrosion, pitting corrosion, crevice corrosion and sour gas service sgs corrosion tests for sulfide stress cracking ssc, csc and hydrogen. The effects of sulfide stress cracking on the mechanical. Lonestar performs a wide range of corrosion and stress corrosion tests in accordance with astm, nace or client supplied specifications. A wide variety of corrosionrelated tests are undertaken to determine weight loss corrosion, intergranular attack, pitting corrosion, corrosion fatigue, stress corrosion cracking, sulfide stress cracking, and hydrogeninduced cracking hic across oil and gas, power, construction, shipping, petrochemical and process industries.
This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. It results in the brittle failure of otherwise ductile materials when exposed to an environment where hydrogen can enter the metal. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. Stress corrosion cracking can be either transgranular or intergranular. The only other environment that has been shown to cause stress corrosion of commercially pure titanium as well as titanium alloys is methanol. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Evaluating intergranular corrosion with metallography and.
Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Ssc is a form of hydrogen stress cracking resulting from absorption of atomic hydrogen that is produced by the sulfide corrosion process on the metal surface. Alkylation units manufacture gasoline blending components by treating light hydrocarbons with strong sulfuric or hydrofluoric acid. Stress corrosion cracking facts and how to reduce the. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Stainless steels are damaged by stress corrosion cracking in conditions containing chlorides at the high temperatures. Element performs sulfide stress cracking ssc testing of metals subject to cracking under the combined action of tensile stress and corrosion in the presence of water and h2s, in compliance with nace tm0177 iso 15156 standards. Ironically, that failure was caused by sulfide stress cracking ssc of a weld repair due to a leak caused by amine scc. The need for more adequate engineering data and a better theoretical understanding of sulfide cracking has led to a more thorough study of several variables involved in the sulfide cracking of carbon steel. Transgranular stress corrosion cracking an overview. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism.
Sensitization, intergranular attack, stress corrosion. Failure again is by intergranular cracking and the mechanism is more likely if bromine, chlorine, or iodine ions are present in the alcohol. It often causes brittle failure of a metal in stress in water mixed with hydrogen sulfide. Stresscorrosion cracking in aluminum alloys is characteristically intergranular. An attempt is made to list the possible sources of contaminants during manufacture, shipping. Tcr engineering mumbai corrosion testing, nace, astm. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Use of austenitic stainless steels in petroleum refining also carries the risk of underdeposit corrosion, pitting, and chloride stresscorrosion cracking where chlorides are present see corrosion, intergranular. The test addresses the resistance of metals to cracking failure under the combined action of tensile stress and corrosion in aqueous environments conatining hydrogen sulfide h 2 s. Intergranular stress corrosion cracking of welded steel twi. Internal stress corrosion cracking of shale gas flowlines. Bruemmer b a departments of nuclear engineering and materials science and engineering, university of michigan, ann arbor, mi 48109, usa b pacific northwest laboratory, richland, wa 993. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment.
A wide variety of corrosion related tests can be undertaken at rajkot metlab services in india to determine weight loss corrosion, intergranular attack, pitting corrosion, corrosion fatigue, stress corrosion cracking, sulfide stress cracking, and hydrogeninduced cracking. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Intergranular sulfur attack in nickel and nickelbase alloy. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment.
Evaluating intergranular corrosion with metallography and xps chemical analysis. Factors affecting the sulfide stress cracking performance. Corrosion behavior of inconel 625 heanjia super metals. Astm a262 intergranular corrosion test igc intergranular corrosion is sometimes also called intercrystalline corrosion or interdendritic corrosion. Sulfatereducing bacteria are active in the absence of oxygen anaerobic.
In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called interranular stress corrosion cracking igscc or simply. There appears to be no unique mechanism of transgranular stress corrosion cracking, since no single factor is common to all susceptible alloys. Gutzeit and johnson 4 reported cracks between 100 and 140 f 37. Environmental cracking season cracking caustic cracking caustic embrittlement stress corrosion cracking scc hydrogeninduced cracking hic hydrogen. Hydrogen sulfide cracking of carbon and alloy steels. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes.
Effects of irradiation on intergranular stress corrosion. In the presence of oxygen aerobic, some bacteria may directly oxidize iron to iron oxides and hydroxides, other bacteria oxidize sulfur and produce sulfuric acid causing biogenic sulfide corrosion. Susceptibility to intergranular attack iga and intergranular stress corrosion cracking igscc of alloy 690 uns n06690 was investigated using chemical etching, doubleloop electrochemical potentiokinetic reactivation dlepr, and slow strain rate tests. Corrosion detection and testing at tcrkuwait in kuwait. Tcr arabia corrosion testing, nace, astm, laboratory. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. It has been shown that h 2 sinduced stress corrosion cracking attack is worst at temperatures around 80c 176f, but cracking can occur also at temperatures below 60c 140f. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620oc to 705oc, depending upon prior solution treating temperature. A wide variety of corrosion related tests can be undertaken at tcr advanced services to determine weight loss corrosion, intergranular corrosion attack, pitting corrosion, corrosion fatigue, stress corrosion cracking, sulfide stress corrosion cracking, and hydrogeninduced corrosion cracking. Other problems that have been observed with inconel include wastage, tube denting, pitting, and intergranular attack.
Alloys for oil field environments must resist sulfide stress cracking, or cracking in the presence of hydrogen sulfides and water in combination with a tensile stress. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Effects of irradiation on intergranular stress corrosion cracking g. Sulfide stress crackingnace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement, liquid metal embrittlement, season cracking, caustic embrittlement, stresscorrosion cracking, stepwise cracking, sulfide. Chloride stress corrosion cracking in austenitic stainless.
Corrosionpedia what is sulfide stress cracking ssc. Sulphide stress cracking is prevented by minimising the hardness and strength of the alloys used for wet h2s systems. Highstrength, highly alloyed materials such as nickelbase alloys are susceptible to this form of attack when coupled to iron, indicating that failures are a result of hydrogen. A wide variety of corrosion related tests can be undertaken at tcrkuwait engineering services in kuwait to determine weight loss corrosion, intergranular attack, pitting corrosion, corrosion fatigue, stress corrosion cracking, sulfide stress cracking, and hydrogeninduced cracking. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel.
The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Traditional austenitic steels are found to be more susceptible to such attack however duplex grades are less prone to it. Selecting alloys for severely corrosive environments. What is astm a262 intergranular corrosion test igc china. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Ssc attack is shown in the following table for various alloys. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. Refinery environment assisted cracking flashcards quizlet. Sulfide stress cracking an overview sciencedirect topics. Tcr offers a comprehensive range of material testing services for corrosion problems that include. Nitronic 50 in both the annealed and highstrength hot rolled conditions has been included in the 1996 revision of nace standard mr01 75 sulfide stress cracking resistant metallic material for oil field equipment, at hardness levels up to rc 35 maximum. In general, however, all susceptible alloys are unstable in the environment concerned but are largely protected by a surface film. Sulfide stress cracking or ssc is an issue in the oil and gas units.
Impact toughness of the casing decreased significantly and intergranular cracking occurred when specimens were maintained at a high stress level of 85%. Hydrogeninduced cracking hic and sulfide stress cracking ssc hydrogeninduced cracking results from the combined action of a tensile stress and hydrogen in the metal. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Woodford department of materials engineering rensselaer polytechnic institute troy, new york abstract the phenomenology of intergranular sulfur attack in nickel and nickelbase alloys and the resulting embrittlement on postexposure. A wide variety of corrosionrelated tests are undertaken to determine weight loss corrosion, intergranular attack, pitting corrosion, corrosion fatigue, stress corrosion cracking, sulfide stress cracking, and hydrogeninduced cracking. Intergranular stress corrosion cracking weld decay knifeline attack kla exfoliation layer corrosion stray current corrosion. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials.
1041 541 1539 867 194 124 809 1263 541 481 509 1289 1115 50 772 243 932 684 382 782 1508 453 336 543 874 376 1142 16 329 423 239 732 1299 155 1086 989